Product ID:EPON CURING AGENT Z
MSDS Date:10/25/1991
FSC:8040
NIIN:01-143-2701
Kit Part:Y
MSDS Number: BVXCJ

SHELL OIL COMPANY

HEALTH, SAFETY AND ENVIRONMENT
HOUSTON, TX 77210
US

Emergency Phone: 713-473-9461/800-424-9300(CHEMTREC)

Info Phone: 713-241-4819/4141/2252 FAX -6511

Preparer: G. A. VAN GELDER

Cage: 54527

SHELL OIL COMPANY

2463 HOUSTON, TX 77210 US

Telephone: 800-231-6950

Cage: 54527

M-PHENYLENEDIAMINE

CAS: 108-45-2

RTECS: SS7700000

Fraction By Weight: 29-31%

ACGIH TLV: 0.1 MG/M3; 9394

4,4'-METHYLENE DIANILINE (SARA III)

CAS: 101-77-9

RTECS: BY5425000

Fraction By Weight: 20-23%

ACGIH TLV: S; 0.1 PPM; A2; 9394

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

4,4'-METHYLENEDIANILINE/PHENYL GLYCIDYL ETHER

CAS: 68391-25-3

Fraction By Weight: 17-18%

1,3-DIAMINOBENZENE/PHENYL DIGLYCIDYL ETHER

CAS: 38353-82-1

Fraction By Weight: 31-33%

LD50 LC50 Mixture:LD50 (ORAL RAT) IS 735 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:PRODUCT IS IRRITATING TO SKIN, EYES,
RESPIRATORY TRACT. IT MAY STAIN SKIN AND CAUSE SKIN OR RESPIRATORY
SENSITIZATION. PRODUCT IS PRESIMED TO BE MODERATELY TOXIC & MAY BE
HARMFUL IF SWALLOWED. MAY CAU SE LIVER AND/OR KIDNEY DAMAGE.
Explanation of Carcinogenicity:4,4'-METHYLENEDIANILINE IS LISTED BY NTP
& IARC. SEE INDIVIDUAL REPORTS FOR DETAILS.
Effects of Overexposure:IRRITATION AS NOTED ABOVE. SKIN SENSITIZATION
EVIDENCED BY RASHES, HIVES. LUNG SENSITIZATION EVIDENCED BY COUGH,
WHEEZING, SHORTNESS OF BREATH. KIDNEY DAMAGE EVIDENCED BY CHANGES
IN URINE VOLUME & APP EARANCE. LIVER DAMAGE EVIDENCED BY LOSSOF
APPETITE, JAUNDICE, AND/OR PAIN IN UPPER ABDOMEN-RIGHT SID.
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE, SKIN &
RESPIRATORY DISORDERS MAY BE AGGRAVATED. SKIN OR LUNG ALLERGIES MAY
INCREASE CHANCE OF DEVELOPING INCREASED ALLERGY SYMPTOMS. IMPAIRED
KIDNEY, LIVER & HEART FUNCTIONS

First Aid:IF ANY IRRITATION PERSISTS OR IS SEVERE, SEE A DOCTOR.
EYE:FLUSH W/WATER 15 MIN, HOLD LIDS OPEN. SKIN:REMOVE CONTAMINATED
CLOTHING AND LAUNDER BEFORE REUSE. WASH WITH SOAP & WATER.
INHALED:REMOVE TO FRESH AIR. RESTORE/AID BREATHING AS NEEDED.
INGESTED:IMMEDIATELY GIVE 2 LARGE GLASSES OF MILK OR WATER & 30 CC
SYRUP OF IPECAC. (NOTHING BY MOUTH IF UNCONSCIOUS.) GET IMMEDIATE
MEDICAL ATTENTION.

Flash Point Method:SCC
Flash Point:>199F,>93C
Extinguishing Media:USE WATER FOG, "ALCOHOL" FOAM, DRY CHEMICAL OR CO2.
Fire Fighting Procedures:WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER
CONFINED AREA WITHOUT FULL BUNKER GEAR & POSITIVE PRESSURE APPROVED
SCBA. COOL FIRE EXPOSED CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard:NITROGEN OXIDES & NITROGEN CONTAINING
ORGANIC COMPOUNDS MAY BE RELEASED UPON COMBUSTION.

Spill Release Procedures:MAY BURN ALTHOUGH NOT READILY IGNITABLE. USE
CAUTION WHEN CLEANING UP SPILL. TAKE UP WITH AN ABSORBENT MATERIAL
AND DISPOSE OF PROPERLY. WATER FLUSH MUST ALSO BE DISPOSED OF
PROPERLY.
Neutralizing Agent:NO INFORMATION GIVEN BY MFR ON MSDS.

Handling and Storage Precautions:STORE IN A COOL, DRY PLACE WITH
ADEQUATE VENTILATION. KEEP AWAY FROM OPEN FLAMES & HIGH
TEMPERATURES.
Other Precautions:WARNING:POTENTIAL SENSITIZER. CONTAINERS, EVEN THOSE
THAT HAVE BEEN EMPTIED, CAN CONTAIN HAZARDOUS PRODUCT RESIDUES.
WASH W/SOAP & WATER BEFORE EATING, DRINKNIG, APPLYING COSMETICS OR
USING TOILET FAC ILITIES.

Respiratory Protection:AVOID BREATHING VAPOR. IF EXPOSURE DOES EXCEED
EXPOSURE LIMITS USE A NIOSH APPROVED RESPIRATOR TO PREVENT
OVEREXPOSURE. USE EITHER A FULL-FACE, ATMOSPHERE-SUPPLYING
RESPIRATOR OR AIR-PURIFYING RESPIRA TOR FOR ORGANIC VAPORS
(29CFR1910.134).
Ventilation:USE VENTILATION AS REQUIRED TO CONTROL VAPOR
CONCENTRATIONS.
Protective Gloves:WEAR CHEMICAL RESISTANT GLOVES
Eye Protection:WEAR CHEMICAL GOGGLES
Other Protective Equipment:WEAR CHEMICAL RESISTANT CLOTHING AS REQUIRED
TO MINIMIZE CONTACT.EYE WASH FOUNTAINS & SAFETY SHOWERS SHOULD BE
AVAILABLE
Work Hygienic Practices:MFR: ? HMIS:USE STRICT CHEMICAL HYGIENE
PRACTICE. AVOID UNNECESSARY EXPOSURE. WASH THOROUGHLY BEFORE EATING
OR DRINKING.
Supplemental Safety and Health
LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. CONTAMINATED LEATHER
ARTICLES, INCLUDING SHOES, CANNOT BE DECONTAMINATED & SHOULD BE
DESTROYED TO PREVENT REUSE. MSDS ENTERED INTO HMIS BY DGSC AT
REQUEST OF GSA.

HCC:N1
NRC/State Lic Num:NONE
Vapor Pres:<1 MM
Vapor Density:>1
Spec Gravity:1.14
Solubility in Water:SLIGHT
Appearance and Odor:DARK LIQUID, AMINE ODOR, MAY CONTAIN CRYSTALS

Stability Indicator/Materials to Avoid:YES
NO INFORMATION GIVEN BY MFR ON MSDS.
Stability Condition to Avoid:STRONG OXIDIZING AGENTS & STRONG LEWIS OR
MINERAL ACIDS.
Hazardous Decomposition Products:NITROGEN OCIDES, CARBON MONOXIDE, AND
UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSE OF PROPERLY. HMIS: DISPOSE OF I/A/W
FEDERAL, STATE & LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.